The number N would increase with decreasing limiting apparent brightness f0, because one is sampling, on average, larger volumes of space when one counts fainter sources.
Further, from the experimental data, derived parameters such as apparent molar volume (Vϕ), apparent molar isentropic compression (Ks,ϕ) and limiting apparent molar expansion (Eφ∞) have been evaluated.
The limiting apparent molar volume, φ0v, and the experimental slope Sv, have been interpreted in terms of solute-solvent and solute-solute interactions, respectively.
The limiting apparent molar volume and limiting slope (Sv) is found to be different for different salts at different solvent compositions and has also been interpreted in terms of ion-ion and ion-solvent interaction.
From the ionic limiting apparent molar volumes and their dependence on temperature it is possible to obtain information about the kind of interactions between R4 N+ ions and sulfolane.
Deviations in the slopes of φv versus √C are observed at higher concentrations of the salt and φvo, limiting apparent molar volume, have been interpreted in terms of solute-solvent interactions.
From the limiting apparent molar volumes, we have calculated φ°ν values using Masson's equation and we have obtained the individual ionic φ°ν (ion) contributions according to the method suggested by Conway, Verral and Desnoyers.
Kinetic simulations suggest that nonequilibrium experiments impose a limiting apparent affinity on the order of KD,app ≥ (texp × kon)−1 (where texp is the incubation time and kon is the chemical on-rate constant) irrespective of the true KD, which may be much lower.
In Ecatepec, too, the limits are apparent.
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