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The German refining company, PCK Raffinerie GmbH, has commissioned Uhde to design and construct a turnkey plant for the etherification of light naphtha with bioethanol in Schwedt, Germany.
Recycling light naphtha in the FCC process is an interesting alternative, which may increase the yield of propylene by 50% if proper processing is carried out.
A new process for selective dimerization of commercial cracked light naphtha (C4 6) into gasoline-range molecules (C7 11) was simulated.
In the present work we report the effect of monoethanolamine (MEA) in the biphasic hydroformylation of the olefin content in a real light naphtha cut from "El Palito" refinery in Venezuela using the Rh/TPPTS system.
The first network was employed to calculate the specific gravity of gas oil, kerosene, Light Naphtha (LN), Heavy Naphtha (HN), gas oil and kerosene flash point and gas oil pour point.
The present work is an evaluation of 1 wt.% Pd/sulfated zirconium pillared montmorillonite catalyst in the hydroisomerization reaction of two fractions of light naphtha composed mainly of C5 and C6 paraffins (feeds 1 and 2).
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It was concluded that low saturated hydrocarbons such as light-naphtha were suitable for hydrocarbons mixed with methanol fuel.
The trend for reactivity and propylene yield was as follows: light cracked naphtha > heavy straight run naphtha > light straight run naphtha > heavy cracked naphtha.
To this aim, light cracked naphtha (LCN), heavy cracked naphtha (HCN) and a PolyNaphtha (PN) oligomerisation product were cracked under a wide range of operating conditions over a commercial Y zeolite based equilibrium catalyst.
The results from this experiments show that light cracked naphtha (LCN) gave the highest propylene yield of 18% at 650 °C, and that propylene yield depends on the naphtha fraction being used as feed.
Results of light FCC naphtha cracking have shown that selectivity towards propylene is governed by hydrogen-transfer reactions.
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