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The effects of reaction parameters and the ligand environment on the polymerization were also investigated.
Kβ X-ray emission spectroscopy (XES) probes charge and spin states of metals as well as their ligand environment.
Catalytic behavior of Ni(I) complex in different ligand environment for hydrogen evolution from acid depends from the ligand nature.
Changing the ligand environment, polymerization parameters also posed a great influence on the catalytic activities and the properties of the resulting polymers.
As the steric bulk at the cobalt center increases by changing the alkyl substituents on the ligand environment, 1,4-cis content decreases.
Yardimci, D., Serna, P. & Gates, B. C. Surface-mediated synthesis of dimeric rhodium catalysts on MgO: tracking changes in the nuclearity and ligand environment of the catalytically active sites by X-ray absorption and infrared spectroscopies.
Similar(28)
In addition, the fluorescence properties of complexes 1 and 2 were rationalized in terms of the local ligand environments in the crystal structures, and magnetic properties of complex 3 are also given.
This is not true for TbIII and HoIII, where symmetrical ligand environments are required, deviations impinging on the relaxation mechanism.
Early work focused on the application of the theories developed by Bleaney to understand the NMR spectra of paramagnetic lanthanide complexes with axially symmetric ligand environments.
The corresponding H and C NMR spectra indicated that this new compound comprised two differentiated groups of resonances indicative of two separate n-butyl and (DippBDI) ligand environments.
The Fe K-edge spectra of NifB-co are nearly superimposable with that of FeMo-co, indicating that the oxidation states and ligand environments of the Fe atoms between these two cofactors are nearly identical.
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