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The electric double layer capacitance was considered for spherical nanoelectrodes operating in acetonitrile-based electrolytes.
The double layer capacitance was about 1 μform2 for all the oxygenated a-C films.
When electrolysis commenced the double layer capacitance was greatly reduced (< 5μF cm−2).
The double layer capacitance was calculated using the following equation: C dl = 1 2 π fmax Rct Open image in new window (5).
The double layer capacitance was found to be close to 40μF cm−2 at open circuit potential.
The specific surface area of the BDD evaluated with the double layer capacitance was enhanced by the excavation of up to nearly 15 times as much pristine BDD electrode.
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The charge transfer resistance and the double layer capacitance were also calculated using EIS data.
VOxNy electrodes can be operated in different aqueous electrolytes, but only double layer capacitance is measured in neutral electrolytes.
Variation of the pore size distribution on the double layer capacitance is explained on the basis of computer simulation.
In the presence of KOH fast and reversible redox reactions take place while only double layer capacitance is observed when NEt4BF4 in acetonitrile is used as electrolyte.
The modification of the double layer capacitance is related to the part of the surface occupied by the bonds between the polymer and the metal (grafting ratio).
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