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In the case of metallic tubes exposed to NO, the intensity is reduced by 17% and the line exhibits an even larger broadening to 0.64 eV.
The exposure to a comparable dosage of NO2 not only induces a larger shift (∼ 150 meV) but also a larger broadening.
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The large broadening of the peaks may be the result of the merging of the peaks of two crystalline modifications.
The resonance of triazole ring proton was not present in the 1H NMR spectrum due to the extremely large broadening (Fig. 3b).
Our XRD studies on the milled NCs indeed show large broadening in the XRD pattern because of the size reduction and development of strain.
However, the hybridization of the defect mode and SPP is not interesting in the sense of decreasing of SPP dissipation due to large broadening of the defect mode [16].
The large broadening was observed for signals located at 7.09 ppm, 5.51 ppm, in the range of 4.3 4.5 ppm and 1.31 1.38 ppm, which were assigned to aromatic protons H2e/H6e, protons of CH 2 group H7e, and protons of the CH 2 groups from fragment CH 2 7c)–N CH 2 6d), as well to the tert-butyl group protons, respectively (Fig. 3a).
In the 1H{13C} gHMBC spectrum recorded at 298 K heteronuclear peaks, a correlation between the proton signals of the CH 2 groups of the fragment CH 2 (7c)–N CH 2 (6d) and a proton signal of triazole ring to the appropriate signals of carbon atoms two or three bonds away was not observed, which was caused by a very large broadening of the proton signals.
Notably, the backbone resonances of residues 1 3, while experiencing very little or no shift in 20% TFE (Fig. 8A) even after a few weeks of incubation (indicating that TFE alone does not alter the conformation of the N-terminus of Ub), undergo the largest broadening upon addition of CuII.
The seemingly large broadening of this affinity peak is due to the sigmoidal dose response character of the bioassay.
Large broadening of the orientation tuning was occasionally observed in our electrophysiological data especially for vertically tuned neurons, and it might be responsible, in part, for the blurring of imaged orientation domains in our work.
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