There is a lack of fundamental studies on chemical kinetics of ultra-lean methane combustion and reliable kinetic schemes that can be used together with computational fluid dynamics studies to design and develop advanced mitigation systems.
The modeling and simulation to design the process have been accomplished by a comprehensive modeling package (GASDS), which includes kinetics of biomass devolatilization and pyrolysis, gasification, and secondary gas phase kinetic schemes.
Convergence is investigated in the framework of kinetic schemes.
Reduced mechanisms are derived based on respective kinetic schemes.
Three kinetic schemes obtained from the literature have been used in this study.
The main novelty of this model are the detailed gas phase and surface kinetic schemes developed.
Therefore, the validation of the available kinetic schemes is of great importance.
Its goal is the analysis of polymerization systems involving complex kinetic schemes in an automated way.
An application to three kinetic schemes coupled with diffusion is presented in a monodimensional case.
This lumping technique is shown to be exact for a variety of kinetic schemes.
This information is represented in the form of chemical kinetic schemes, kinetic rate parameters, and thermodynamic databases.
