Exact(8)
Results are interpreted in terms of a nucleation and growth mechanism under two different kinetic controls.
Quartz precipitation is suppressed and dissolved Si concentrations are limited by chalcedony equilibrium with no kinetic controls.
Nevertheless, one may think of kinetic controls on solid-solution formation, which may result in solid compositions, which should on the basis of thermodynamic considerations not be achievable (Shtukenberg et al. 2006) (i.e. inside the spinodal gap).
Correspondingly, natural and experimental (Ba,Sr SO4 crystals with compositions inside the miscibility gap would reflect non-equilibrium partitioning, which, considering the kinetic controls affecting solid-solution precipitation, seems plausible as well.
This paper presents small-scale push pull tests designed to evaluate the kinetic controls on SO2−4 reduction in situ at mixing interfaces between a wetland and aquifer impacted by landfill leachate at the Norman Landfill research site, Norman, OK.
There are likely kinetic controls not captured by thermodynamic analyses.
Similar(52)
Knowledge about such changes can generally be deduced from knowledge of the stereochemistry (three-dimensional structures) of the starting materials, intermediates, and final products (provided these are obtained under kinetic control).
It leads to stronger kinetic control characters on those samples.
The obtained data shown in Fig. 5 supplies the further evidence for OLA-induced kinetic control.
Using the single capillary arrangement, the reaction was shown to be operating under kinetic control.
The diffusion coefficients steadily increase from 773 to 1,073 K, corresponding to the region of the kinetic control.
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