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Fig. 10 Schematic illustration of NH3-sensing mechanism of (a) rGO and (b)~(c) ZnO/rGO film sensor, in which (b) and (c) shows the adsorption sites of ZnO/rGO film with proper and excess rGO amount, respectively, and the magnified view in (b) is the formed accumulation heterojunctions at the interface.
Based on the above reports, the enhanced NH3-sensing performances of ZnO/GO film sensor at room temperature are proposed in this present work, which should be ascribed to two aspects, one is the supporting role of ZnO nanoparticles layer (as illustrated in ref 22) and the other is the formed accumulation heterojunction at interface between rGO and ZnO.
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