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The controlling step for vaporization of arsenic is diffusion through the melt.
If the rate-determining step is diffusion through the adsorbent, then the following equation is valid: F = 1 - 6 / π 2 exp - B t (5)and F = q t q ∞ (6).
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Similarly, in the coated particles the rate-limiting factor was diffusion through the coating membrane.
The rate-limiting factor of the uncoated resin particles was diffusion through the core matrix.
The optimized batch of beads released, 68% of metformin over 12 h, following the Higuchi's release kinetics with the mechanism of release being diffusion through the matrix.
Another rate limiting step with a reaction rate proportional to the electrode area would be diffusion through the Pt thin film – most likely along Pt grain boundaries [26,28].
The mechanism of labelling has been shown to be diffusion of 99Tc through the cell membrane followed by binding to haemoglobin in the presence of reducing agent.
Because the void network is disconnected, diffusion through the cells must be taken into account for effective diffusion in the tissue.
In drug release study, the critical step is drug diffusion through the SLN matrix; however in skin permeation, rate limiting step is traversing the pathway through the skin.
Uptake of azole antifungal drugs is believed to be via passive diffusion through the cell wall and is affected by modification of cell wall structure by altering the glycosylation of surface proteins.
The wastes produced by metabolism are broken into ammonia, which is eliminated by diffusion through the mantle and lophophore.
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