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Changes in n and absorbance, k, are, as expected, wavelength-dependent, but in general n greatly increases (to 1.65 1.80); this is also rationalized using the Lorentz oscillator model, since the wavelengths employed are to low energy of a strong absorption in neutral polypyrrole at ca 390 nm.
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Moreover, affinity of the new compounds was also rationalized in terms of their interactions with the enzyme.
The influence of nitrogen incorporation in the carbon matrix on Pt NPs/support interaction was also rationalized on the basis of density functional theory simulations.
This clustering of the substrates based on P450 activities is also readily rationalized in terms of their chemical structures.
35c Compared to the aforementioned N-alkyloxaziridines, this barrier is lower and the difference in energy is also generally rationalized by assuming that conjugation of the planar nitrogen with the alkoxycarbonyl group lowers the energy barrier of the transition state.
As Uber continues to work through a huge amount of internal management turmoil, the company is also consolidating and rationalizing more of its international business.
The effect of particle size spread is examined, and the model is also used to rationalize long standing mineral dressing rules on sorting and sizing of particles.
It is also difficult to rationalize, that if the unique length of M. burgessensis and P. zenobia chaetae evolved as effective sensory tools against predation, why haven't similar sized structures been employed in a similar manner by subsequent brachiopod lineages?
Ease of oxidation was also computationally rationalized using DFT approach showing increased ease of oxidation with electron donating functionalities.
There is also a drive to rationalize healthcare access, which in radiology is focused on reducing unnecessary imaging that does not have a clear impact on patient care.
On the other hand, there are also mechanisms rationalizing an effect from firm size to productivity growth: expanding firms may invest in new technologies, learn about more efficient methods of production, use more specialized inputs, and/or better coordinate their resources.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com