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We also analyze the addition of Meso-Carbon Micro-Beads (MCMB) particles on the reversible and irreversible capacities of new three-dimensional, hybrid electrodes.
The capacities are much larger than the theoretical value of CoFe2O4 (912 mAh g−1), and the extra irreversible capacities can be attributed to the solid electrolyte interphase (SEI) films [42].
However, the significant initial irreversible capacities observed in the voltage profiles of such layered nanocomposites arise mainly from the oxygen loss occurring at extended charge cycling (> 4.5 V) [12, 14].
Due to the formation of Sb and Si oxides during the synthesis process which would react with lithium in the first discharge cycle, the irreversible capacities are also increased.
A linear relationship between the reversible and the irreversible capacities has been established showing the interdependence between the lithium storage capability of graphite powders and the lost capacity due to surface chemistry.
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Irreversible capacity.
This results in high irreversible capacity and short cycle life.
The first cycle irreversible capacity loss also decreased upon substitution.
Such storage state is advantageous to reduce irreversible capacity.
With this strategy the irreversible capacity could be compensated effectively.
However, the system possesses significant irreversible capacity of around 22%.
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