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The results demonstrated that hydrogels were produced with broadly designed swelling degrees typically ranging from 500% to 2000%, which were significantly dependent on the relative concentration of polymers and irradiation time for crosslinking.
XRD study confirmed the formation of monoclinic (α-phase) and body-centered cubic (γ-phase) of Bi2O3 with variation of MW irradiation time for 10 min and 15 min respectively.
Low amounts of residual peroxide and iron, which were below the limit allowed by Brazilian environmental legislation, were attained after 360 min of irradiation time for both artificial and solar sources.
The model aimed at preliminary prediction of the adequate setting of the processing parameters (typically the laser irradiation time) for laser polishing of a metal with known geometric surface consisting of micro-asperities and material properties.
Microwave (MW) and ultrasound-assisted COD determination methods have been optimized by means of experimental design and the optimum conditions are: 40 psi pressure, 855 W power and 1 min irradiation time; and 90% of maximum nominal power (180 W), 0.9 s (s−1) cycles and 1 min irradiation time for microwaves and ultrasound, respectively.
Although the fixed-bed reactor requires comparable irradiation time for total inactivation of bacteria than that corresponding to the slurry system, it shows minor deactivation and allows the continuous operation without the need of particles removal, making this immobilised system a good alternative to successfully scale-up the photocatalytic disinfection technology.
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The difference shown between the optimised irradiation times for the formation of the photoproducts allowed us to propose a time-resolved photoactivation method, for the simultaneous determination of binary mixtures, based on the use of different linear calibration curves established at various irradiation times depending on the mixture to be resolved.
The slurry system shows a higher inactivation rate at the beginning of the reaction that decreases progressively, whereas the fixed-bed reactor increases the inactivation rate as the irradiation time increases, leading both catalytic systems to comparable irradiation times for the total inactivation of bacteria, i.e. concentration below the detection limit.
The irradiation times for 5 × 359 MBq 111In are comparable to those of 90Y: 237 and 414 h.
Color plots of the CNDs solutions excited with different irradiation times for a 355, b 532, and c 1064 nm.
Figure 3 Absorption spectra for (a) MB and (b) MO solutions for different irradiation times for the TiO 2 /Si-template samples.
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