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The dominant portion of combustion samples was not vaporized, thus the iron phase solidified from the liquid.
Improved stability is therefore due to gold particles being in contact with an iron phase such as FeO(OH); calcination removed the stabilisation.
Characterization of high resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD) and Mössbauer spectra showed that two different types of iron phase were discerned in the spent Na Fe3O4 catalyst, with 32.4% of Fe3O4 and 67.6% of χ-Fe5C2 phase (Fig. 2c f; Supplementary Table 5).
However, because iron can be present in the form of different phases in the olivine structure, e.g. iron oxide or metallic iron, a clear understanding of the link between the iron phase and catalytic activity of olivine is essential.
The iron phase is shown to be drained to levels considerably below that of the taphole and this is demonstrated to have an important effect on operating liquid level in the furnace.
The primary iron phase dissolves.
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The components of iron phases were identified based on their Mössbauer parameters including isomer shift, quadruple splitting and magnetic hyperfine field.
This characteristic is proved to be consistent with the iron phases and their volume fraction formed in these two zones.
Iron phases were shown not to affect the porous structure of EG or its sorption capacity.
The iron phases entrapped in the as-synthesized carbon nanotubes consist of γ-iron, α-iron, Fe3C and Fe1−xS.
Iron contents and other synthesis parameters were varied to evaluate the evolution of the observed iron phases.
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