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Fig. 1: An overview of the in-source resonance ionization spectroscopy study of radiogenic mercury isotopes.
Here, by applying resonance ionization spectroscopy, mass spectrometry and nuclear spectroscopy as far as 177Hg, we determine 181Hg as the shape-staggering endpoint.
To extend our reach beyond the range of previously studied mercury isotopes, it was necessary to use the most sensitive laser spectroscopy method available at ISOLDE: in-source resonance ionization spectroscopy.
High-resolution resonance ionization spectroscopy (RIS) is required for laser spectroscopy and trace analysis of short-lived and long-lived radioactive nuclei.
We have proposed high-resolution resonance ionization spectroscopy in a gas jet combined with a narrow band-width injection-locked Ti Sapphire laser.
Ground-state and isomer charge radii and magnetic moments were studied by performing resonance ionization spectroscopy on the mercury isotopes with unprecedented sensitivity, reaching as far as 177Hg, an isotope with a half-life of only 127 ms and a production rate of just a few ions per minute.
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Resonance-ionization spectroscopy (RIS) is an extremely sensitive and highly selective analytical measurement method.
(The duty cycle is the ratio of the number of atoms irradiated in a given volume to the total number of atoms entering that volume). For further discussion, see spectroscopy: Resonance-ionization spectroscopy.
The aluminiumIII complex formation equilibria studied by potentiometry, electrospray ionization mass spectroscopy (ESI-MS), quantum-mechanical calculations and 1H NMR spectroscopy are here described and discussed, and the structural characterization of one of these new ligands is presented.
Preliminary identification of these compounds rested on high-resolution electrospray ionization mass spectroscopy (HRESIMS) and nuclear magnetic resonance (NMR) (Supplementary Tables 3 5, Supplementary Figs. 3 50).
The new tripod ligand and the cage were characterized by multinuclear NMR and electrospray ionization mass spectroscopy.
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