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Mean Spherical Approximation theory is used to calculate the necessary Onsager coefficients and ionic activities.
This is despite large changes in ionic activities and water activity at the liquid junction boundary and assumptions of ideal behaviour of the Henderson equation.
Measurements of ionic activities of H+, Mg2+, Ca2+, and Cl− measured by emf in solutions of varying water activity provide a rational set of ionic hydration numbers.
A new system of basic equations was used, which do not contain the individual ionic activities and the inner potential of the electrolyte.
This work demonstrates the perfect analogy between the standard method for determining activities in non-electrolyte mixtures and the method used for the determination of ionic activities in electrolyte solutions.
While the mean ionic activity of an electrolyte may be experimentally obtained by means of procedures based on equilibrium thermodynamics, reliable values of individual ionic activities are obtainable only by using procedures in which the electrolyte is not in equilibrium.
Similar(48)
Calcium ions react with carbonate ions to form calcium carbonate as the ionic activity product exceeds its thermodynamic solubility product, and re-precipitates on the active sites of nacre powder surfaces.
The mean ionic activity factor variations prove to be substantial.
After attempts to record ionic activity of a single yeast cell were unsuccessful, they doused the cell in ethanol to try to elicit a response.
The role of junction potential and the ionic activity in voltammetric response was analysed.
Data are obtained for the mean ionic activity coefficient of NiCl2 in the mixed solutions applied.
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