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The phrase "intimate relation with" is grammatically correct and can be used in written English.
It is commonly used to describe a deep, close, and personal connection or involvement with someone or something. Example: "The artist had an intimate relation with his work, pouring his heart and soul into every stroke of the brush."
Exact(17)
The tensile behaviour of the blends and composites are in intimate relation with the morphological characteristics of these materials.
Niamh Cusack multilayers Kenton's longing for a more intimate relation with her colleague, shattered when her ploy to goad him into action by threatening to marry another misfires.
Previous analysis revealed that granules are composed of a complex aggregation of sub-units in intimate relation with an intracrystalline matrix.
Meningiomas of the clinoidal region pose significant surgical challenges due to their close proximity and intimate relation with surrounding critical neurovascular structures.
In addition to the "intimate" relation with fifth amendment values, the obtaining of private papers by the government touches upon the first amendment and the generalized right of privacy.
For this volume, Ganahl invited a series of authors who have an intimate relation with each country he visited to contribute texts or interviews addressing the consequences of (cultural) exchange, globalization, nationalism, multinationalism, Orientalism, Eurocentrism, tourism, languages, theory, desires, identity, and politics from a variety of perspectives.
Similar(43)
He wanted to forge more intimate relations with fewer companies.
For millennia, most humans survived through more or less intimate relations with land and sea.
"She could not have intimate relations with people," Ms. Klieman said.
They bond human communities and they assist in forging intimate relations with the broader Earth community.
A first encounter with Frederick Tuckerman puts the reader into surprisingly intimate relations with a stranger.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com