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At the end a theoretical description of the possible origin of the attractive interactions between like-charged surfaces mediated by charged macroions with distinctive internal charge distribution is given.
"It does affect me in the sense that [the customers] will call and dispute an internal charge – like a travel insurance charge – that they never signed up for, and then we will have to address that," he said.
The proposed sensing mechanism might be attributed to the decrease in internal charge transfer band.
BISBS chemi-sensor was designed based on internal charge transfer (ICT) fluorescence mechanism.
Internal charge transfer (ICT) and photoinduced electron transfer (PET) mechanisms are responsible for these changes.
A ratiometric fluorescent chemosensor 5 was designed and synthesized based on internal charge transfer (ICT).
The photochemical mechanisms examined are photoinduced electron transfer, internal charge transfer and excimer formation, with emphasis on the first category.
Interestingly, either the internal charge transfer or the energy transfer in the hybrid material contributes to photoluminescence (PL) quenching of the CdSe moieties.
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The copolymer achieves a relatively low bandgap (1.6 eV) by its internal charge-transfer, which concurs with the results of density functional theory (DFT) calculation for the distribution of HOMO and LUMO levels.
Computational study by the AM1 method has been performed for pyrene-based donor acceptor-substituted systems, with the aim to elucidonor acceptor-substitutedolarity-dependent fluoresystemsgoverned by mesomeric and twithed inthenaimcharge-toansfelucidateand theT, resp).
The 'internal charge mediator' character of the graphite felt in the composite electrode, therefore, provided a large faradaic current response.
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