Sentence examples for intermolecular processes from inspiring English sources

Both t-alkoxyl radicals underwent very fast unimolecular processes (β-scission) essentially to the exclusion of intermolecular processes (addition and H-abstraction), in contrast to other t-alkoxyl radicals such as t-butoxyl radicals.

These cyclopropanations occur through intermediates such as 41 or 42 for intermolecular processes, in a concerted although highly asynchronous manner.

The free energy barriers for these intermolecular processes, leading to a cis arrangement of phenyl and bromide, were in a narrow span between 42.6 kcal mol 1 (for 2t1ts) and 48.5 kcal mol 1, (for 4t1ts).

The activation energies for the intermolecular process range from 0.265 to 0.012 eV and for the intramolecular process from 0.380 to 0.047 eV, depending on the pyrolysis temperature.

It can indicate which particular atoms are involved in the reaction; in rearrangement reactions it can show whether an intramolecular or intermolecular process is involved; in exchange reactions it can show that particular atoms of, for example, hydrogen are exchanging between the reacting species.

This progresses from an intra- to an intermolecular process, eventually leading to precipitation (cf. Fig. 4).

On the one hand, the polymer structure contained fewer –OH group and slowed the dehydration intermolecular process.

The fate of the second electron is currently unknown; however, it is known to disproportionate very quickly and this could be intramolecular rather than an intermolecular process.

In the intermolecular process, there will always be a considerable amount of free nucleophile in solution and therefore coordination of the nucleophile does not shut down the external anti-pathway as is done in the intramolecular case.

For oligomeric proteins this balance is further complicated by the fact that, whilst aggregation must be avoided, at the same time oligomerisation to give the final active species is also an intermolecular process.

This can occur as either an intramolecular or an intermolecular process, where coevolution arises from the evolutionary interaction between sites within a single molecule in the former, and the latter is due to co-adaptation as a result of the evolutionary interaction between different molecules (Juan et al. 2008; Lovell and Robertson 2010).