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The fluorescence properties revealed the presence of intermolecular excimer formation.
A novel quinoline based tripodal receptor that shows intermolecular excimer emission has been designed and synthesized.
Filtered-up rubrene NPs treated at 170°C and 180°C exhibited blue luminescence due to the decrease of intermolecular excimer densities with the rapid increase in size.
Upon association with dimyristoylphosphatidylcholine (DMPC) discoidal complexes, the intramolecular excimer was replaced by intermolecular excimer fluorescence due to proximity between pyrene moieties on A8C and A138C in neighboring apoLp-III molecules on the discoidal particle.
This is consistent with the random incorporation of 6 and 7 in an isolated fashion into blend gel fibres preventing intermolecular excimer formation.
As the proportion of pyrenylalanine gelator is increased, a new intermolecular excimer band forms due to association between adjacent pyrenylalanine gelators.
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The decrease of specific surface area with increasing particle sizes reduced the density of intermolecular excimers [40].
Ligands 1 and 3 containing naphthalene units can be used as fluorescent sensors as they form intra- or intermolecular excimers in the presence of appropriate dicarboxylates.
Compared to the monomer emission of 1-pyrenemethanol (Py-OH), the emission spectra of BPy-POSS in dichloromethane show the large proportion of intramolecular and intermolecular excimers due to the formation of pyrenyl dimers or aggregates via the easy rotation of two adjacent ether bonds and the π π interaction of pyrene rings, respectively.
In contrast, 1,4-dicyano-2(4′-methylbenzyloxy methylnaphthalene (3), which is a DCMN–p-xylene dyad, forms a fluorescent intermolecular DCMN–DCMN excimer in the crystalline state (blue, λfexcimer="4′-methylbenzyloxy methylnaphthalene
This suggests that the emission arises from intermolecular rather than intramolecular excimer formation.
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