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The intermolecular approach used here seems to be rather flexible and appealing to design interface oriented fluorescent sensors to convene different analytic purposes for a wide variety of anion targets.
The intermolecular approach offers excellent synthetic flexibility because no tethering of the oxidant is required, and its reduced form is not tangled with the product.
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Lipshutz, B. H. & Keith, L. M. A stereospecific, intermolecular biaryl-coupling approach to korupensamine A en route to the michellamines.
Interestingly, the energies associated with "emerging" intermolecular interactions often approach those of conventional intermolecular interactions suggesting these may be competitive in directing the way molecules assemble in the condensed phase.
Compression in these materials generally occurs by large decreases in intermolecular distances (often approaching 10 percent per GPa), in contrast to minimal intramolecular compression.
Still, this number clearly illustrates a problem with which all intermolecular correlated mutation approaches have to deal, i.e. that many interactions will be missed and/or incorrectly assigned.
In the simplest approach, the intermolecular potential is spherically averaged and used to determine Lennard Jones parameters.
The formation of functional groups of non-volatile oligomers by the thermal degradation of polyisobutylene is characterized by a kinetic approach including intermolecular hydrogen abstraction of primary (p) and tertiary (t) terminal macroradicals (Rp and Rt) and volatile small radicals (S), followed by β-scission.
The d200 spacing of the intermolecular hydrogen-bonded plane approached that of the ideal crystal at relatively low annealing temperatures in the block copolymers.
An approach for studying intermolecular interactions is to employ a model potential.
Hence the resultant 2D asynchronous spectra generated by using the DAOSD approach can reflect intermolecular interaction reliably.
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