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Insights into bond strengths, kinetic and thermodynamic selectivities, and the nature of the intermediates involved will be examined.
It has commonly been argued that the high-energy intermediates involved in photochemical transformations limit the opportunities for effective stereocontrol.
The intermediates involved in the conversion of the starting materials to nanocarbon products were estimated; the nanocarbon formation routes are discussed.
Based on the theoretical calculations, transition states and structures of reaction intermediates involved in the catalytic cycles are derived.
Those factors controlling the two processes are discussed in terms of metal oxygen intermediates involved in the catalysis.
The activation barriers of key elementary steps and the adsorption configurations of key intermediates involved in acetic acid hydrogenation on Cu(111) surface were investigated.
Metabolomic assessment showed that dietary VA caused a restoration of metabolic intermediates involved in energy metabolism that were affected by dietary PAH.
Accordingly, compared with control cells, PARP14-depleted cells accumulated less glucose-6-phosphate and 2-PG, two key glycolytic intermediates involved in nucleotide and serine synthesis (Fig. 3h 2,4,42.
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The interconversion between oxygenated C1 surface intermediates involves the reversible reaction of methoxide to dioxymethylene via dehydrogenation and nucleophilic attack of surface lattice oxygen.
A formulation is presented for the reaction between two solid species which proceeds through gaseous intermediates, involving the net generation of gases.
Therefore, adsorption of these intermediates involves two phenomena: bonding and antibonding interactions in agreement with the Hammer and Norskov model for adsorption [23].
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