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At low and intermediate scan rates, sigmoidal waveforms were observed for nanowire arrays indicating very fast mass transport.
Emergent anomalous Randles Sev˘cik behavior is observed for intermediate scan rates that depends not only on DH but also on ℓ and ℓτ.
In CSCV, the anomalous intermediate scan rate window of Randles-Sev˘cik plots shifts with the number of charge transfer step.
At low scan rates, the reduction is under the kinetic control by the chemical step, while the voltammetric wave becomes reversible at high scan rates and a mixed chemical-diffusion control is observed at intermediate scan rates.
At intermediate scan rates such as 50 mV s−1, the profile of the CV is similar to that depicted in Fig. 3b for the first cycle, that is, two current peaks can be well distinguished, one corresponding to the reduction of Mn(IV) to Mn II) at −0.10 V (vs. SHE) and a second oxidative peak at 0.6 V (vs. SHE) corresponding to the oxidation reaction.
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These intermediate scans could represent cases with mixed DLB/AD pathology.
Regional measures were derived by dividing each scan series into three groups: outer scans, intermediate scans and inner scans (Fig. 1b).
Data import filter options were set at: 400 (minimum mass), 5000 (maximum mass), 0 (grouping tolerance), 0 (intermediate scans), and 1000 (threshold).
Data import filter options were set to 400 (minimum mass), 5,000 (maximum mass), 0 (grouping tolerance), 0 (intermediate scans), and 1,000 (threshold).
MS/MS peak lists were generated using lcq_dta.exe from the BioworksBrowser v3.3.1 SP1 (Thermo Fisher Scientific) with the following options applied: grouping tolerance, 0; intermediate scans, 0; minimal scans per group, 0; precursor charge state analysis, auto.
Because intermediate scans to determine the exact timing of progression were not performed, and arterial disease improved or stabilized at subsequent angiography, we had no proof of progression beyond 6 months, and therefore classified the course of arteriopathy as TCA in these three patients.
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