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For c-NiPS3, slower kinetics of reduction first led to the formation of an intermediate richer phosphorus-containing nickel phosphide phase, Ni5P4 at a temperature of reduction of 623 K while Ni2P started being formed at 773 K.
bRecruitment (muscular contraction): 0, absent; 1, simple; 2, weak intermediate; 4, rich intermediate.
To estimate reproducibility, the second rating was later dichotomized to "placebo" or "PTH" (the latter comprising intermediate and rich callus).
These have shown that the development of an intermediate chromium-rich phase provides protection under low temperature hot corrosion conditions, while the aluminium-rich surface layer provides resistance to high temperature oxidation and type I hot corrosion.
At higher substrate temperatures, an intermediate Ga-rich regime is observed, leading to smooth droplet-free surfaces28.
However, a large fraction of the intermediate, hydrogen-rich PAH has decomposed upstream of this point.
The coating is therefore designed with an intermediate chromium-rich interlayer, which permits the rapid formation of chromia healing areas of type II corrosion damage.
The intermediate Cr-rich layer can form a Cr2O3 scale to provide good protection under the hot corrosion conditions in the Na2SO4 salt fluxing at 900, 950 and 1000 °C.
Surprisingly, we observed the formation of an intermediate "water-rich" GO layers at 25 °C with an interlayer spacing of approximately 15.2 Å, which was caused by the intercalation of two additional layers of water into the interlayers of the GO membrane.
The interface between the first graphene plane and the SiC surface is composed of an intermediate C-rich layer having covalent bonds with Si atoms of the substrate [13 15].
It consists of a bonding layer, a Cr-rich intermediate layer and an Al-rich outer layer.
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