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Density functional theory calculations for the surface intermediate of this copper-catalyzed process provide mechanistic insight into the effects of the functionalization scheme on surface coverage.
Surface of the Co3O4/CeO2 nanocomposite during complete oxidation of CH4 in the temperature range of 200 500 °C and potential stable intermediate of this catalysis were identified with ambient pressure X-ray photoelectron spectroscopy (AP-XPS).
The degradation intermediate of this transaminase reaction is 4-hydroxy-phenylpyruvate, which in turn is oxidized in the presence of vitamin C to homogentisic acid.
After structural elucidation, we concluded that the new compound was an E/ Z mixture (2/7)[ 27] of sulfenylated allylic alcohol 5 (Scheme 4),[ 28] which was found to be the true intermediate of this reaction (see below).
In T. reesei, the first identified pathway intermediate of this second d-galactose pathway was galactitol, which was discovered due to its transient accumulation during growth on d-galactose or lactose in a galactokinase deletion strain (Seiboth et al. 2004).
In A. nidulans, l-sorbose was found to accumulate during growth on d-galactose but was absent in strains with a loss-of-activity of l-arabinitol dehydrogenase (araA1), which suggests that l-sorbose is an intermediate of this d-galactose pathway in A. nidulans (Fekete et al. 2004).
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However, this intermediate of the implemented oxidative pathway was re-consumed in the third growth phase leading to more biomass formation.
The initial structure for evaluating the reaction intermediates of this asymmetric synthesis was constructed on the basis of the optimized ab initio transition state structure (MP2/6-31+G∗ MP2/6-31+G∗ lithium amide LiNH2 and propene oxide.
Taking the importance of the modification of oxygen reduction reaction in fuel cell activity into consideration, the adsorption energy and the stable adsorption sites for the intermediates of this reaction in Au (100) and bimetallic Au/M (100) (M = Pt, Cu, and Fe) systems were closely examined.
Future studies should investigate other proposed intermediates of this pathway, including melatonin's antioxidant actions and immunomodulatory functions.
Some of the intermediates of this process, the trivalent intermediate arsenicals, MMA3+ and DMA3+, have been implicated in arsenic toxicity, acting as potent cytotoxins and enzyme inhibitors.
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