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The interfacial reaction mechanism is discussed.
Therefore, it can be said that carbon coating is an effective strategy to fully suppress the interfacial reaction and gassing on the LTO surface.
It may result from the interfacial reaction at the initial growth stage.
The overall rate of reaction seems to follow interfacial reaction controlled kinetics.
No interfacial reaction was observed between the aluminium matrix and SiC particles.
For particles smaller than 1 μm, the interfacial reaction resistance was dominant.
The degree of interfacial reaction depends on the reinforcement composition.
A nanoscale carbon coating along with a stable solid electrolyte interface (SEI) film around LTO is seen most effective as a barrier layer in suppressing the interfacial reaction and resulting gassing from the LTO surface.
The reacted surface of LTO is also covered by a SEI film with ~2 nm in thickness resulting from the interfacial reaction, which is much thicker than that of LTO soaked under Condition A (Fig. 3b).
The SEI film on LTO electrode is formed gradually with the processing of interfacial reaction, which leads to the decrease in the continuous gassing rate of LTO based battery accordingly.
In this paper, interfacial reaction and strengthening mechanism of Au80Sn20/Cu joint by rapid solidification reflow soldering were studied.
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