Sentence examples for insertion products from inspiring English sources

The reactivity of the alkynyl functional group in the insertion products can also be exploited.

The process provides a transformative mode of anilines since the group insertion products are versatile precursors through simple conversions to a range of nitrogen-containing aromatic molecules.

This process provides a transformative mode for anilines, and the insertion products are versatile precursor to various nitrogen-containing aromatic molecules through simple conversions.

We are delighted to observe the formation of 4-hydroxymethyl-substituted TMM insertion products 34 and 35 when acetone and water was used as a mixed solvent.

In general, the reactions lead to the insertion products, alkyl or alkenyl, which have a limited chemistry.

To demonstrate the synthetic utility of this TMM insertion process, we explored a number of selective transformations of the insertion products with a view to the synthesis of functionalized nitrogen-containing aromatic molecules (Fig. 6).

For example, reaction of 2,4-dimethylaniline provided the 4-methoxymethyl-substituted TMM insertion product 23 in 71% yield.

When phenylamine was employed as substrate, the reaction failed to afford the TMM insertion product but gave rise to the corresponding spiro intermediate as the major product.

The insertion product 24 bearing two ortho-methyl groups undergoes reduction and a radical sp3 C H amination reaction to form 2,3,4,5-tetrahydro-1H-benzo[c]azepine 5066.

Under the optimized conditions, the one-pot reaction of N-tosyl protected p-toluidine provided the TMM insertion product 3 in 68% yield (Fig. 2).

In the mononuclear counterpart, the styrene 2,1 insertion product results in the deactivation of the metal centre.