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Its free-radical crosslinking can be initiated either by initiator system [24, 25] or by high energy irradiation [26 28].
Ammonium persulfate-N,N,N′,N′-tetramethylethylenediamine (TEMED) redox initiator system was used to initiate the polymerization reactions as well as to create charged groups in the aged gels.
In this study, thermal initiation was replaced with a redox initiator system to decrease the set time of the HIPEs.
The polymerization of styrene was carried out as a free-radical emulsion polymerization in the presence of redox pair initiation system, potassium persulphate/sodium bisulphite as an initiator system and dodecyl benzene sodium sulphate as an emulsifier.
This dual initiator system ideally could imitate XDT.
The crosslinking was done with a 10 mol% of a free radical initiator system.
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All parameters involved in the model are calculable using the kinetic constants of the initiator initiation system and the thermal initiation system.
In order to assign the soluble fraction signals unmistakably, PPGE samples had to be synthesized using various cationic initiator systems.
It was found that such initiator systems are highly effective in reducing free vinyl acetate but organic by-products are produced.
The sensitivity of reactor output and product molecular properties to various process variables, i.e., initiator systems, initiator injection modes, reactor jacket and ethylene inlet temperatures, reactor pressure, and ethylene split ratio can be projected using this model.
Among the many initiator systems available for photopolymerization, only a few have been identified as suitable for cell-based hydrogel formation owing to their water solubility, crosslinking properties and non-toxic reaction conditions.
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