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In a photopolymer bearing NAS/HABI system, an improvement of the photosensitivity was observed by the addition of co-initiator, 2-mercaptobenzothiazole (MBT), to the initiating system.
Quasiliving ATRP of n-butyl acrylate with rapid quantitative initiation was found by the ethyl-2-bromoisobutyrate (Et-2BriBu /CuBr/PMDETA Et-2BriBu /CuBr/PMDETATF.
The simple gold-AP initiating system is interesting and needs further developments.
A first additive, triethylaluminum, is needed to favour the homogeneity of the initiating system in the solvent of reaction.
These macromers were then photopolymerized at 450 nm using a visible light initiating system to produce crosslinked degradable networks.
The influence of the nature and concentration of the initiating system and the presence or not of a buffer were studied.
Similar(17)
Insurgents have used a wide variety of initiating systems to trigger detonations.
We have selected three surface-grafted aryl initiating systems (aryl = benzoyl phenyl (BP), dodecylphenyl (DDP), aminophenyl (AP)).
When compared with CQ/amine initiating systems, the combination of CQ and benzodioxole compounds caused lower Rp but the comparable final double bond conversion.
Further, PBIEM macroinitiator was used to initiate the copolymerization of a binary mixture of tBuMA and DMAEMA through both ATRP and AGET ATRP initiating systems, yielding densely grafted copolymers with statistical distribution of the side chains.
The mechanism was discussed for different multicomponent initiating systems.
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