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With increasing mean crystallite sizes to about 18 nm at higher heat-treatment temperatures, the full width at half maximum of the observed distributions decreases and becomes even narrower than the LSW function.
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XRD diffraction lines were shifted and broadened, indicating increasing stress and decreasing mean crystallite size, from 109 nm for coatings deposited at relative oxygen concentration equal 0% to 23 nm at 20%.
It is observed from Table 1, the mean crystallite sizes increase with the increasing of the calcination temperature, which refers to the more crystalline structure.
Warren Averbach Fourier transfer analysis of the diffuse reflections indicated that the mean crystallite size increased and micro-strain decreased significantly with the rise in firing temperature.
The dimensions of face-centered cubic unit cell for MgO samples decreased while crystallinity and mean crystallite size increased with calcination temperature.
Annealing at 400 °C results in crystalline anatase TiO2 matrix with its mean crystallite size decreasing with increasing the [Au]/[Ti] ratio in the composite layers.
The increase of the oxygen content leads to a decrease of the mean crystallite size of the nanocrystalline cubic (B1 structure) Cr O N phase and to an enhancement of the (002) preferred orientation.
The mean crystallite size of the Au-nanoparticles is slightly decreasing from 17 21 nm to 10 13 nm with increasing deposition temperature from 260 to 300 °C.
Therefore, ZnO nanoparticles with about 100 nm of mean crystallite size were obtained.
The mean crystallite size calculated from the XRD patterns has been found to be in the range of 1.80 to 2.45 nm with the increase in molar concentration of the capping agent.
Table 1 Mean crystallite size and lattice strain of the ball-milled MgH2 Time of ball-milling (h) Mean crystallite size (nm) Lattice strain 0 87 – 10 58 0.72 30 35 0.95 40 32 1.07.
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