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Even at the increased discharge current of 20 A g−1, the cell with CN@P-Si electrode delivers a high specific capacity of 1904 mAh g−1.
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The alloy electrode sintered at 2 GPa shows superior high rate dischargeability and the gentlest capacity decrease with increasing discharge current density.
Ra also increases with increasing discharge current.
Also Cαβopt increases with increasing discharge current density.
For all samples, there is a monotonous capacity decrease with the increasing discharge current.
It is seen that with the increasing discharge current the neutral density decreases and the metastable state density increases.
In the case of PPy nanotube electrodes, a decrease in the specific capacitance with increasing discharge current is observed.
The diameter and depth of crater increases with increasing discharge current and pulse-on time and hence increases the surface roughness (Hewidy et al. 2005).
The nearly constant specific capacitance of the ZnO nanorod core-PPy sheath electrode with increasing discharge current density is suggestive of faster redox kinetics at the interface.
The significant capacitance decrease with increasing discharge current density is likely to be caused by the increase of potential drop due to electrode resistance and the relatively insufficient Faradic redox reaction of the Mn3O4/Ni foam composite under higher discharge current densities.
The ratio of electrochemical polarization to concentration polarization during discharge (ηe/ηc p increases with the number of charge/discharge cycles due to the faster decline in electrocatalytic performance (I0) than in the apparent diffusion coefficient DαA, but the ratio decreases with increasing discharge current density and state of discharge (SOD).
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