Sentence examples similar to incipient bond from inspiring English sources

The second feature is the antisymmetric stretch character of the (selected) reaction coordinate, i.e. compression of the incipient Cl Me bond forming neutral Cl Me, and expansion of the breaking Me Cl' bond forming the departing chloride anion; this involves a rapid charge flow from the attaching chloride to the departing chloride in the presence of the "frozen" hydrating water molecules.

In all cases, it has been found that the dehydrogenation (desaturation) process is initiated by a kinetically important hydrogen activation step at the carbon of the incipient double bond which is closest to the acyl terminus of the fatty acid chain.

In this transition state, the forming six-membered ring adopts a boat conformation with greater eclipsing interactions about the incipient C C bond than in endo- TS-A.

The incipient C N bond therefore arises principally from the interaction of the imine lone pair with the aryl π* adjacent to the carbon, which is the signature of a classic SNAr attack.

From the s- trans enamine, formation of the Michael endo diastereomer was computed to occur via chair-shaped TS-A, with a staggered conformation about the incipient C C bond.

This places the amide N 33)H in an orientation to make a weak incipient intramolecular hydrogen bond to O(4).

While members of the enediyne family of natural products exhibit remarkable structural diversities, all enediynes contain a core consisting of two acetylenic groups conjugated to a double bond or incipient double bond within the nine- or 10-membered carbocycle (Fig. 1).

That the nanotube should act as a template for the incipient graphitization suggests that bonding and strength for load transfer may be developed at these interfaces.

Jim Baertschi, 54, detects all the signs of an incipient boom.

Another ray of light came from housebuilding stocks, which outperformed the S&P 500 index by more than 20 percentage points in the first quarter.Perhaps the most encouraging sign has been an incipient rebound in the corporate-bond market.

Incipient metals: functional materials with a unique bonding mechanism.