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The maximum in the first shell peaks of Fe O histogram shown in Fig. 6 were used for the Fe OII distances.
Anisotropy in the first shell responses results from the fact that the analysed microvolumes are not necessarily averaged for the responses of all crystal orientations in the aragonite.
Upon elastic loading, a small fraction of bonds in the first shell is broken in the loading direction whereas some new bonds are formed in the transverse direction.
Fitting results (Table 3) indicate that precipitated Zn is present in an octahedral environment with 6 O atoms at an interatomic distance of 2.08 Å in the first shell.
They found that nearly all EMI+ ions show a concentrated orientation in the first shell, i.e., parallel to the surface, but a nearly isotropic orientation in the second shell, as shown in Fig. 12c.
The fitting results of EXAFS data indicate that ammonia and water molecules can coordinate directly in the first shell of zinc extracts, thus decreasing the hydrophobicity of zinc extracts and inhibiting their distribution.
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After in situ reduction in H2/He, the first shell Rh Rh coordination number increases and no more oxygen is observed, indicating the formation of Rh metal particles.
Specifically, in ferroselite the first shell Se atom is at a much longer bond distance than the three iron atoms, while in dzharkenite this is reversed.
Paths for the first (In O), second (In–In), and third (In–In*) were used in the three-shell model; only the first shell was used in the one-shell model.
Slip stitch to the center dc of the first shell, * shell in the next sc, sc in the center dc of the next shell.
In the actinoid elements the added electrons also go into an f orbital, in a similar manner but in the fifth shell instead.
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