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Although the mobility of the ion is hindered by the decreased diffusion coefficient, as the ion gets closer to the protein's surface, its residence time increases, enabling it to skim over longer distances in the 1st shell than in the 2nd one.
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We note that the magnitude of the near-field induced carrier generation in the Cu2O shell depends on the density of states on the exposed surfaces33.
We found that calculated |E(r)2| in both the Al core and in the Cu2O shell (Fig. 4b) qualitatively reproduce the measured EQE spectrum (Fig. 4a).
Atom probe tomography showed that the Dy content at grain boundaries (GBs) was close to that in the (Nd,Dy 2Fe14B shell.
The nitrogen adsorption/desorption analyses and TEM observation of the hollow particles confirmed the presence of disordered mesopores in the LaBO3 shell domain.
Oxygen ion conductivities in the ZrO2 shell were obtained by regression of the experimental CO2 uptake curves with the model and are consistent with the literature data.
A layer-wise approach has been identified with the direct imposition in the 3D shell model of equilibrium conditions for transverse stresses and compatibility conditions for displacements.
The dual mechanisms of carrier generation either in the Al core with subsequent injection into the Cu2O shell and/or the direct excitations of hot carriers in the Cu2O shell, as suggested by the calculations in Fig. 4b both provide enhanced hot carrier densities for chemical transformations.
This increase is owing to the decrease in the number of defects in the Fe3O4/CdSe shell.
On the other hand, the decrease in the SiO2 shell thickness and increase in crystalline Si core diameter may result in the formation of straight Si NWs.
Therefore, the TCS in the Cu2O shell caused by oxide volume extension will be larger than the results without participation of catalyst and humidity, thereby creating larger RSG.
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