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M2+ ion fractions in different coordination polyhedra and structural disordering among the Li and M sites in the as-prepared pyrophosphates were studied in detail by a multi-technique approach.
A rich variety of molecular complexes or extended multi-dimensional networks (1D, 2D, 3D) has been identified and depends mainly on the equatorial connectivity of the uranyl cation (UO22+) in different coordination numbers (tetragonal, pentagonal or hexagonal bipyramid).
The HCpIDC3- and CpIDC4− anions exhibit two coordination modes (μ4 kN,O: kN′,O′: kO″,O‴: kO″″ and μ5 kN,O: kN′,O′: kO″,O‴: kO″″: kO) in different coordination environments.
Generally, they exhibit a rich structural chemistry with interesting physical and chemical properties, and, in contrast to zeolites, which are built of [SiO4]4− and [AlO4]5− tetrahedrons, their frameworks embody metals in different coordination.
The most significant change during the temperature-induced SCSC polymorphic transition from 1a to 1c (monoclinic, I2/a) is the Eu O bond cleavage resulting in different coordination geometries of Eu atoms in 1a and 1c.
All of compounds 4 6 display 3D framework with diverse topology constructed from the tda3− ligands in different coordination modes and secondary ligands (or bridging atom) connecting metal ions.
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Copper species with different reducibility and isolated Cu2+ ions in different coordinations were identified by H2-TPR and the ESR techniques respectively.
Unlike the sulfonamides the anions may bind to the metal ion in three different coordination geometries: trigonal-bipyramidal geometry, tetrahedral geometry, or in a distorted tetrahedral geometry.
The larger deviations are usually unavoidable by using any set of parameters, and are usually for (1) the low/high coordinations of ions observed in many different coordination numbers (e.g. Tl+, alkali metal ions), (2) structure refinements of dubious quality, and (3) configurations with very little data.
The chelate size variation results in a markedly different coordination behavior towards Pt II).
But in (2) two different coordination modes like bidentate chelating and bidentate chelating bridging modes are observed.
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