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Originally existing as localized lone-pairs in the layered-like crystalline structure, Te-p electrons hybridize with empty Fe-d orbitals to generate p-d antibonding states below the Fermi level in the amorphous phase, which shifts up the amorphous phase valence band and results in delocalization of the valence band electrons to account for the concurrent anomalies.
Moreover, loss of CAL1 prevented centromeric localization of newly synthesized CenH3CID and resulted in delocalization of CENP-C [20].
Therefore, the hydroxyl group cannot participate in delocalization of π-electrons or function as an electron donor.
del Toro et al. (35) demonstrated that a mutation in huntingtin reduces interaction with OPTN Rab8 complex, resulting in delocalization of the complex in Golgi and impairment of post-Golgi trafficking.
The U Hubbard term in GGA+U allows charges to be localized onto particular ions of mixed-valence systems, while pure GGA results in delocalization of charge over all metal atoms.
Apoptotic signaling leads to activation of caspases (casps), which specifically cleave native proteome substrates after aspartate residues, resulting in delocalization of proteins, loss or gain of function, or loss of complex formation.
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This anomalous phenomenon is rooted in the delocalization of Te-p electrons in the amorphous phase.
Although the RBR was dispensable for the interaction with PRC1, its disruption resulted not only in a delocalization of SCML2A from chromatin, but also in decreased PRC1 occupancy at several target genes.
It is likely that ligands are intimately involved in modulating the redox chemistry and are also involved in the delocalization of the electron density as the cluster is oxidized.
The prepared poly amic acid) and polyimide doped with HCl exhibit a large enhancement in the dielectric constant in comparison to that of traditional polymers, ascribed to the improvement in charge delocalization of the polymers by introduction of the conjugated oligoaniline segments.
The interaction of Ru → M, corresponding to the delocalization from 4d orbital of Ru to s valence orbital of M2+, results in the delocalization of P Ru → M, which decreases the electron density of P nucleus and causes the downfield 31P chemical shifts.
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