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α-Phenyl-2-pyridinemethanol was totally converted to 2-benzoylpyridine with a selectivity of 96% in dioxane/water 50/50 vol% in the presence of a 2.7%Pt 0.99% Bi/C.
A number of hits comprising a novel series of p-chlorobenzene-caprolactam sulfonamide compounds demonstrated concentration dependent and APP > Notch selective inhibition of gamma-secretase, as exemplified by ELN158162, which displayed an IC50 in gammaAPP assay of 0.65 μM, compared with an IC50 of approximately 25 μM in the gamma Notch assay, resulting in a selectivity ratio of approximately 40.
Increase in excess of methanol significantly reduces the concentration of phenol in the feed, thereby leading to reduction in the rate of reaction, which results in lower conversion of phenol characteristic for the subsequent reactions and in a lower selectivity of dimethyl derivatives in favor of the intermediate product - o-cresol.
The aggregated NiO particles resulted in a CO selectivity of less than 100%% owing to CH4 formation, regardless of synthesis method of catalyst.
During acute experiments on rats we showed that inhibition of the intraperitoneal synthesis of nitric oxide resulted in an increased selectivity of the peritoneal permeability and an increased net ultrafiltration [ 32].
Deletion of the trigger loop in Escherichia coli resulted in a 100-fold decrease in selectivity of ATP over dATP (Zhang et al, 2010) and mutation of Q1078 to either asparagine or serine is lethal in yeast (Kaplan et al, 2008), consistent with a key role of this residue in NTP/dNTP discrimination.
This leads to a strong change in the receptive field and, as a consequence, to a change in orientation selectivity of the membrane potential.
All considered, a likely mechanism of αBgTx action appears to involve a change in the selectivity of the nicotinic channel, which would increase its ability to carry potassium ions.
The activation of Mn3+ or Mn4+ based active sites leads to a shift in selectivity of the ORR process towards 2 electron formation of hydrogen peroxide.
