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Core shell catalysts have shown improved activity for hydrogen production, enabling reduced catalyst loadings, while reactive spray deposition techniques (RSDT) have been demonstrated to enable manufacture of catalyst layers more uniformly and with higher repeatability than existing techniques.
Directed evolution resulted in a GOx mutant I115V with 1.4 1.5-fold 1.4 1.5-foldimprovedr β-d-glucose (Vmactivity7.94 to 10.81 μmol min−1 mg−1; Km ∼ 19–21 mM) and oxygen consumption kinetics correlate well [Vmax (O2) form 5.94 to 8.34 μmol min−1 mg−1; Km (O2) from 700 to 474 μM].
Mutations significantly improved activity for shorter versions of F2A but could decrease activity in the case of T2A.
Open image in new window Fig. 1 Scheme for the synthesis of CANHCS with hollow macroporous core and hierarchical micro-mesopores as highly active metal-free electrocatalysts with improved activity for the ORR via a direct four-electron reaction pathway.
For applications of IREDs as cell-free catalysts, (i) we created an IRED variant showing an improved activity for NADH.
The improved activity for CO oxidation over samples with heterogeneous Pt distribution is likely due to less tendency towards CO self-poisoning through the development of steeper concentration gradients in the Pt containing regions in the porous support material.
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Understanding catalyst function to improve activity for the oxygen evolution reaction (OER) is key to increasing the overall efficiency of electrochemical water splitting, a promising method for sustainable and clean production of hydrogen.
The Chicago Fed reports improved activity (pdf) for July, and American auto dealers grew in 2011 for first time in a decade.
The development of new organometallic complexes with lower toxicity and improved activity is important for improved patient treatment options (Reedijk, 2003).
After two rounds of error-prone PCR and backcross with parental DNA, three mutants were identified for improved activity toward pyrene and for the first time a new activity toward chrysene in comparison to the wild type enzyme.
Chemical composition engineering is one of the most valid approaches to regulate the active sites for improved activity.
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