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They're no happier than Kent Reliance, but given the impressive yields they've been enjoying, they'll manage.
Following purification by size exclusion chromatography, to remove the non-interlocked macrocycle and axle byproducts, rotaxanes 4 a⋅NO 2⋅OTf and 4 b⋅NO 2⋅OTf were isolated in impressive yields of 51%and45%45 %, respectively, and characterized by NMR spectroscopy, mass spectrometry, and HPLC (see Supporting Information (SI) and Figure 1).
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At 5.52%, Pfizer's impressive yield passes with flying colors.
While NbTaTiVW shows an impressive yield strength of 1420 MPa with fracture strain of 20%, NbTaTiV exhibits exceptional compressive ductility at room temperature.
The impressive yield numbers, he adds, will likely serve as a baseline for future studies, because agricultural scientists are making rapid strides at creating new, higher-yielding switchgrass strains.
Although an impressive yield (66.3%) of the products was obtained the process utilized high pressure (84 × 10 Pa of air) and very long reaction times (24 h) [ 27].
Directed or programmed self-assembly of ssDNA can produce junctions and polyhedral cagelike structures as well as highly complex shapes such as smiley faces and ornate map projections in impressive yield.
In the case of 2, the coupled product 2-methoxybiphenyl was obtained in an impressive isolated yield of 98.0%.
Intramolecular reaction of Boc-protected homoserine furnished the γ-lactone in an impressive 87%% yield (entry 13).
To assess our reasoning, we synthesized diphenylphosphinomethanethiol (4) and found that it facilitated the same coupling in a much more impressive 85% yield over two steps.
However, further experimentation revealed that a combination of the Barleunga reagent 61 with HBF4 ⋅OEt2 at 0 °C afforded the desired E-isomer exclusively in an impressive 96%% yield (Scheme 17).
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