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Classic studies on CORs suggest that stereocenters remote from the point of initiation can impact the selectivity of the cascade.
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This freedom of movement potentially impacts the selectivity of migrants.
The tungsten deposition temperature has an impact to the selectivity of the process, where at 450°C nucleation was observed on the silicon nitride surface.
Both MTBE and butyraldehyde decrease the ethanol reaction rate due to competitive surface adsorption on active sites but have no impact on the selectivity of the ethanol partial oxidation reaction.
Our results show that medium engineering has a high impact on the selectivity of ThDP-dependent enzymes as well as on the final product concentration and is therefore a good tool for complementing enzyme and reaction engineering in biotransformations to improve or vary an enzyme for a certain reaction.
Although these original irreversible inhibitors inactivate cathepsin L, it appears that the nature of the warhead drastically impact the selectivity profile of the resulting covalent inhibitors.
The retro-disproportionation and nitrous acid decomposition reactions appeared to impact the selectivity upon the conversion of nitrites to nitrates.
The impact of catalyst acidity on the selectivity of upgraded biomass pyrolysis products was studied by passing pine pyrolysis vapors over five ZSM-5 catalysts of varying acidity at 500 °C.
This small difference can impact the subtype selectivity of the peptides.
For the selectivity of the ApPDCE469G often an impact was found, which is commensurate to an increase of cosolvent concentration.
Let me tell you about the selectivity of this question.
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