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For a model of an ideal chain in a slit-like pore exact equations and a number of approximate formulae for the distribution coefficient K of these polymers are derived.
The free energy and force profiles in nondilute solutions were found to deviate considerably from the ideal chain theory; the perturbation of chains by a presence of the slit walls were substantially reduced in nondilute solutions.
Equations for the distribution coefficient of heteroarm stars are derived by using a model of an ideal chain in a slit-like pore; these equations together with those previously reported for linear block-copolymers are applied to describe chromatography of such copolymers.
By using a model of an ideal chain with point-type defects in a slit-like pore we derive equations for the distribution coefficient covering all modes of chromatography of functionalized polymers of any molar mass in both narrow and wide pores.
We recall that ideal chain complex from [6].
By an ideal chain complex of algebras, (X,d) we mean one in which each Im di+1 is an ideal of X i.
Similar(51)
In contrast to ideal chains, the compensation point where K=1, relevant to critical chromatography, was found to be a function of the chain length.
The depletion effect relevant to colloid stabilization was found in dilute solutions to be slightly weaker for excluded-volume chains than for ideal chains.
The classical tube-reptation (TR) model is based on the assumption, that in entangled polymer melts diffusion takes place inside the effective tubes having a conformation of ideal chains and being stable on the time scale of the terminal relaxation time τt, the latter being strongly molar mass (M) dependent.
Alternatively, the ChG of binary As S system demonstrates an obvious tendency to keep ideal chain-crossing arrangement built of As2S6 NFC (Z = 2.25, Δl = 0) character for highly homogeneous structural network, where all trigonal AsS3/2 pyramids are interconnected via the same double-Ch atoms =As S S As= links.
The coefficient υ is 0.5250, which is close to 0.5, establishing the fact that the PEG chains behave much like ideal chains in the solution [23].
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