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(i) Formal modeling and verification.
A plot of log I versus the Co II)/(I) formal potential gives a volcano curve that also includes catalysts studied previously.
The M II)/(I) formal potential of MN4 macrocyclic complexes dictates their electrocatalytic activity for many reactions and L-cysteine oxidation is not an exception.
A correlation of log i (at constant potential) versus the M II)/(I) formal potential for M= Fe,Co) of the catalysts gives a volcano curve.
A correlation of log i (at constant potential) versus the Co II)/(I) formal potential of the catalysts gives a volcano curve.
We have investigated the effect of the Co II)/(I) formal potential of CoN4 macrocyclics complexes on the catalytic activity of a series of Co porphyrins and Co phthalocyanines for the electrooxidation of l-cysteine.
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In 0.50 M lithium nitrate, even at submillimolar concentration of Tl(I), the formal potential of CuHCF was shifted to more positive values.
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