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Kotsina, N., Kaziannis, S. & Kosmidis, C. Hydrogen migration in methanol studied under asymmetric fs laser irradiation.
For small alcohols, four distinct pathways involving hydrogen migration and H2 roaming prior to H3+ formation are uncovered.
Okino, T. et al. Coincidence momentum imaging of ultrafast hydrogen migration in methanol and its isotopomers in intense laser fields.
Nakai, K., Kato, T., Kono, H. & Yamanouchi, K. Communication: Long-lived neutral H2 in hydrogen migration within methanol dication.
Three intramolecular hydrogen migration reaction paths leading to the formation of H2S were designed.
This observation is in agreement with the formation of H3+ from acetone14, in which hydrogen migration is not favorable and H3+ is solely produced from terminal methyl groups.
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Interestingly, this pathway was initiated with the migration of an α-hydrogen to the β-carbon prior to the ejection of neutral H2, i.e. α-hydrogen migration preceded the ejection of two β-hydrogens.
1,6-Hydrogen migration in the bay region formed by nearby carbon atoms provides an alternate route for both the processes to proceed.
However, several events that are expected to occur during the oxidation of quinoline such as formation of a bond between the equatorial oxygen and the quinoline carbon, cleavage of quinoline carbon-hydrogen bond, migration of hydrogen from quinoline carbon to the sulfido terminal of the active site, and conversion of quinoline to 1-hydro-2-oxoquinoline were neither known nor described.
Adsorbed hydrogen induces migration of sulfur and promoter atoms between adjacent clusters.
All possible hydrogen atom migration, hydrogen atom and hydrogen molecule desorption from single layer graphene have been studied systematically by using functional density theory B3LYP/6-31G B3LYP/6-31G
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