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This dark-coloured, insoluble product of bacterially altered plant and animal detritus is the source of most hydrocarbons generated in the later stages.
The hydrocarbons generated are predominantly oil.
In other words, molecular and isotopic compositions of hydrocarbons generated at steady state can be distinct from hydrocarbons generated at pre-steady state.
Table 1 The distribution of C1-C5 hydrocarbons generated from Mowry shale, 100°C.
Our research has focused on hydrocarbons generated at steady state over geologic time.
Sum wt is wt C1-C5 hydrocarbons generated in the hour indicated, (g/g shale hr) × 109.
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The premise that methane should be independent of the solid hydrocarbons generating it could be flawed.
However, there is nothing to suggest that methane actually reacts with solid hydrocarbons generating new compounds.
However, the non-separated hydrocarbons generate droplet emissions in the domestic ethylene plant site.
With methane in equilibrium with ethane and propane [7], it should come as no surprise that it would be in equilibrium with the solid hydrocarbons generating it.
During the first stage, biogenic methane is the only hydrocarbon generated in commercial quantities.
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