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In this study, the least observed homogeneous rate constant (kobs) belongs to pHs 5.0 and 9.0.
In case (ii), A-t curve shows a maximum depending on the ratio of homogeneous rate constants kfto kb.
The heterogeneous rate constant is relatively high and compares well with the homogeneous rate constant on the basis of the equation of Marcus.
The observed homogeneous rate constant (kobs) for Michael addition reaction was estimated by comparing the experimental cyclic voltammetric responses with the digital simulated results.
In addition, the observed homogeneous rate constant of catalytic reaction of electrochemically generated 4,4′-diphenoquinone with glutathione (or N-acetylcysteine) was investigated using digital simulation method.
Moreover, the RDCP response is always peak-shaped, even for very high homogeneous rate constants for which the stationary response in cyclic voltammetry has a sigmoid feature.
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Molecular hydrogen could be produced up to higher temperatures than in the case of homogeneous rates.
In other words, GPs who participate in teleconsultations not only refer fewer patients, they exhibit more homogeneous rates of referral.
While most of the regions were assumed to have homogeneous rates, an artificially elevated risk was induced in a randomly selected group of areas.
Table 1 shows that, according to Akaike and Bayesian information criteria, the mixture model is more appropriate for our data than the model with homogeneous rates.
Under the assumption of homogeneous rates, the ML estimation of the death rate was 8.59 ± 0.03 deaths per nucleotide substitution at 4-fold degenerate sites per microsatellite (hereafter all rates mentioned use this metric).
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