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A physico-chemical approach is developed, which can be used in binary diffusion couples to determine diffusion parameters of product phases with a wide homogeneity range, as well as phases with a narrow homogeneity range.
The homogeneity range has been established for Ba(Au1−xSix 2 (AlB2 type, extending from BaAu0.4Si1.6 to BaAu0.9Si1.1).
Studies performed on the NdVO4 BiVO4 system showed the existence of the BixNd1−xVO4 homogeneity range for x ⩽ 0.49(1).
A behaviour not described earlier has been observed: at cooling inside the assumed homogeneity range of GaAs the growth of As precipitates followed by their dissolution.
For non-stoichiometric compositions, constitutional defects such as vacancies for Mo-rich compositions and anti-site defects for Mo-lean compositions control the homogeneity range.
Both a large temperature-dependent homogeneity range of the β-hydride and a small hysteresis in the formation-decomposition of the β-hydride have been revealed.
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The concept of "average thermodynamic factor" was extended to model binary compounds with certain homogeneity ranges.
A two-sublattice model was used to describe wide homogeneity ranges of the ternary C14 and C15 Laves phases.
Most carbides can be deposited in a wide range of compositions within their homogeneity ranges by a fine-tuning of the Me/C60 flux.
A corrected version of the hafnium-nitrogen phase diagram is presented which contains better information on the homogeneity ranges of μ-Hf3N2 −x and ζ-Hf4N3 −x.
Homogeneity ranges were measured from the phase bands of the diffusion couples by means of EPMA and the results are presented in the form of a phase diagram.
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