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The highest turnover frequency reached 3600 h−1 using ethanol as a solvent.
The highest turnover frequency was obtained with a catalyst bearing average ruthenium particle size of ca. 3 nm.
Among various solid acids, partially Cs-ion exchanged tungstophosphate (Cs2.5H0.5PW12O40) showed the highest turnover frequency, i.e., the initial reaction rate per acid site.
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Notably, a high turnover frequency (TOF) value (1230 h−1) for bifunctional catalyst Zn-PPBCl was achieved via adjusting reaction variables.
A high turnover frequency of 11,800 h−1 with an enantiomeric excess of 79.5% was acquired in acetic acid.
In addition they have high turnover frequency values (TOF) and better selectivity than the corresponding homogeneous catalysts.
This nanocatalyst showed high turnover frequency for Baylis Hillman, acylation and silylation reactions and could also serve as efficient catalyst for various other nucleophilic reactions (Fig. 17) [73].
They showed a high turnover frequency (42.94 h−1) and low Ea value of 15.1 ± 2 kJ/mol for DMAB dehydrocoupling in the ambient conditions.
An extremely high turnover frequency (1370 h− 1) for epoxycyclooctane was achieved, and Co3InaBDC3 exhibited excellent stabilities in 5 recycles without any loss of its catalytic performance.
A high turnover frequency (TOF) of 4.9 × 10−3 s−1 per metal atom was obtained over Co3O4/CuO-3 HPNCs, which is comparable to those published cobalt based catalysts.
The Rh/g-C3N4 catalyst exhibits a high turnover frequency of 969 mol H2· (min·molRh)−1 and a low activation energy of 24.2 kJ/mol.
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