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All preheated carbon-supported palladium catalysts showed very good activity and selectivity to CH2F2 in CCl2F2 (CFC-12) hydrodechlorination, up to 90% at the highest reaction temperature.
The maximum hard coke value of 4.85 wt%, which was found at the highest reaction temperature of 270 °C, was 27 times higher than that at the lower temperatures of 210 and 230 °C.
Deactivation of the catalyst is observed only at the highest reaction temperature, being probably related to deposition over the fiber surface of pyrolytic carbon from cracking reaction of dimethyl ether.
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COx are predominant products only at the highest reaction temperatures (just above 700 K).
Higher reaction temperature and pressure lead to higher reaction rate.
Nevertheless, there are disadvantages such as high reaction temperature and outgrowth of desired product [28, 39].
Ethylene is formed at higher reaction temperature (400 500 °C) on using Co Al mixed oxide.
In a commercial unit, the high reaction temperature is achieved by raising the catalyst circulation rate.
At a higher reaction temperature (480 °C), the hollow capsules were prepared.
The selectivity towards methyl formate (S m %) was more pronounced at high reaction temperature.
Biomass feedstock with high concentration was gasified successfully at high reaction temperature.
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CEO of Professional Science Editing for Scientists @ prosciediting.com