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The samples with the most homogeneous Ni distribution exhibited the highest hydrogen uptake capacity.
Among them, MCNF carbonized at 1200 °C shows 0.73 wt.% of the highest hydrogen uptake at 77 K and 0.1 MPa.
It is suggested that MWNTs with low crystallinity and SWNTs with large diameters and open tube ends yielded the highest hydrogen uptake capacities.
Moreover, the highest hydrogen uptake of 0.38 wt.% exhibited the sample with Pd content of about 35 wt.%, the broadest Pd nanoparticle diameter distribution of 2 14 nm and the highest average Pd crystallite size of 7.6 nm.
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These results may be helpful in designing and synthesizing new ZIFs with higher hydrogen uptake capability.
The activated carbons showed high hydrogen uptake, due to increased porosity (>0.364 nm).
Particularly, high levels of zeolite-like ordering favoured micropores of size <15 Å which are favourable for higher hydrogen uptake capacities.
The isotope exchange observed between the H-loaded metal catalyst and the D2 gas phase demonstrates the significantly higher hydrogen uptake capability of Pd-based catalysts.
The analysis performed shows that framework with elongated triptycene exhibits two times higher hydrogen uptake at 77 K and 1 bar from the gravimetric basis and more impressively four times higher from the volumetric basis: (3 wt% and 127 V/V) than unmodified (base) structure (1.5 wt% and 37 V/V).
The sulfur-doped microporous carbons exhibit isosteric heat of hydrogen adsorption up to 9.2 kJ mol−1 and a high hydrogen uptake density of 14.3 × 10−3 mmol m−2 at −196 °C and 20 bar, one of the highest ever observed for nanoporous carbons.
The combined result is unusually high levels of hydrogen uptake at near-ambient temperatures and pressures (e.g. up to 0.8 wt.% at 25 °C and 2 MPa).
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