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On the 4 ML Pd@Au, which exhibits the highest deactivation rate, the COads coverage is the largest.
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The catalyst has a bimodal particle size distribution and exhibits a high deactivation rate.
It was found that the active metal particle size has a significant influence on the catalyst deactivation for MGP oxidation; the uniform catalyst with higher dispersion shows a higher deactivation rate than the egg shell catalyst.
Especially the Fe/MnO catalyst pretreated with CO showed a much lower deactivation rate and a higher FTS activity than an Fe/Cu/K catalyst in the presence of H2S.
When applied in the methanol to olefins (MTO) reaction, small ZSM-5 crystals obtained in the hierarchical ZSM-11-seeded system exhibited both a high selectivity to C2= C4= olefins and a low deactivation rate.
From equation (7), a small value for k FBB can reduce the dephosphorylation rate of CheB, this in turn increases the deactivation rate of the receptor complex, thereby ensuing high precision.
Catalyst deactivation rate was found to be more than five times faster for the high metal Boscan feed compared to the conventional atmospheric residue from Kuwait export crude.
Deactivation rate order.
Deactivation rate constant (h−1).
High surface area and larger pore volume, due to the more severe dealumination process and acid leaching, reduced the hard coke content, thus slowing the deactivation rate.
The relationship of deactivation rate with weight hourly space velocity (WHSV) was investigated in a wide range of CHO concentrations under high gas superficial velocity.
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