This mutant, in particular, also exhibits the highest conversion levels to the Q photoproduct of any bBR mutant created to date.
They led to very high skeletal isomerization selectivities at 200 °C at high conversion level without any observable deactivation.
(A) Without any treatment (wild type), the dynamical system transitions from the initial instable state (embryo, yellow dot) stochastically towards a final stable state with a normal conversion level (0, blue dot) or towards a final state with a high conversion level (0.92, red dot).
It is shown that development of a special combustion device with high conversion level of fuel chemical energy to useful radiant energy is required, to improve further the system efficiency.
Further, we show that an empirical relation for coke formation and asphaltene conversion gives a reasonable description of the kinetics and prediction of the cracking behavior at high conversion level or long residence time, and that this method is much simpler.
(A) With no treatment (wild type), only extreme phenotypes (normal or high conversion levels) are stochastically produced.
Without treatment (wild type, Fig. 3A), the embryos stochastically develop normally (blue dot, 99% of simulations) or high conversion levels (red dot, 1% of simulations).
At high conversion levels, approximately 80%, the coke reaction order starts increasing until reaching a value of 1 at conversion close to 1.
At very high conversion levels (>80%), both kp and kt decreased with increasing DVB content at a given conversion, consistent with reaction diffusion being the dominant termination mechanism.
